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What you are trying to do is sign-in to your account on the website, and there change the password that you use for Windows Live Mail. They demand that you have two passwords , your existing one (used to sign-in on their website) *and* a new one (used to sign-in in Windows Live Mail).
Find and download Windows Live Mail. If you’ve been using Windows Live Mail, you might want to give the Windows Mail app a try. If you sign in to your PC with your Microsoft account, your email address is already set up in the Mail app.